This appeal is from a decision of the Patent Office Board of Appeals1 affirming the examiner’s rejection of claims 1, 4, 14, and 15, of appellant’s application serial No. 197,702, filed May 25, 1962, entitled “Siliconized Ferrous Products and Processes for Same.” Claims 5 and 7-11 have been allowed.
The invention of the appealed claims is the process of forming an adherent, silicon-containing coating (“ease”) on ferrous metal articles.
It has long been known that iron and steel articles with surface coatings (cases) of high silicon-iron alloys have certain desirable properties, including resistance to abrasion and corrosion. However, the tendency of the silicon-containing case to separate from the iron or steel core has limited the commercial use of articles so coated. Appellant has discovered that this spalling does not occur when the core article— the article on or in which the coating is formed — has “a stable body centered cubic crystal structure,” e. g., an “alpha-delta” alloy. The appealed claims read:
1. The process of providing a metal article with an adherent silicon-containing ease which comprises, maintaining a ferrous base metal alpha-delta alloy article at elevated temperatures while contacting with a siliconiz-ing reagent for impregnating the surfaces of said alpha-delta alloy with silicon to form a case containing silicon upon an underlying core, said alpha-delta alloy having a stable body centered cubic crystal structure in sufficient amounts in its solid solution phase to suppress allotropic transformations in the temperature range up to about 2,000 °F. for reducing stress-rupture between said case and said underlying core.
4. The process of Claim 1 in which said alpha-delta alloy is a steel alloy.
14. The process of claim 1 in which said alpha-delta alloy contains at least about two percent by weight silicon.
15. The process of claim 1 in which said alpha-delta alloy contains at least about one percent by weight aluminum.
The following reference is relied on:
Henderson et al. 2,501,051 March 21, 1950
Henderson discloses the siliconizing process used by appellant. In fact, appellant’s specification refers to the Henderson patent for an example of the method he adopts.2 Henderson, however, forms a silicon-containing case for a variety of core articles, cast irons, “alloy irons,” “alloy steels” including those containing chromium, and, even nonferrous metals, “particularly copper.” Alpha-delta alloys are not disclosed.
The board held appellant’s claims un-patentable under 35 U.S.C. § 103, it being obvious, in the board’s view, “to carry *251out the conventional siliconizing operation on a particular alloy * * The board relied, inter alia, on seven of our recent decisions including In re Larsen, 292 F.2d 531, 49 CCPA 711, (1961) ; In re Albertson, 332 F.2d 379, 51 CCPA 1377, (1964); In re Neugebauer, 330 F.2d 353, 51 CCPA 1138, (1964).
We think the last of these is controlling. The appellants in that case argued that the application of a novel photo-conductive coating to a conventional electrically conductive substratum in the conventional manner was itself a patentable process. They urged:
* * * while it may be obvious to prepare the article by coating once the article is known, it certainly can not be obvious to prepare the article by such a process when the article is unknown and, absent appellants’ disclosure, there is nothing to teach the claimed article.
We rejected that argument and held that the unobviousness of the final product was not determinative of the unobviousness of its method of manufacture.
In the case at bar, it is the substratum (with its consequent more permanent adhesion) rather than the coating which is new. Obviously, this distinction does not warrant a different result with respect to process patentability. We therefore affirm.
Appellant would distinguish In re Larsen,3 supra, and, we suppose, by analogy, In re Neugebauer, supra, as “based upon the proposition that once certain compounds had been conceived, the process by which they were made was obvious.” Appellant argues:
By contrast, in the process of the present invention, the unique feature of preventing rupture between the iron layers is achieved during the process for producing the articles, as set forth above. The novel process is essential to the present invention.
We cannot agree. The unique features of any composition or article of manufacture, not found in the starting materials yet inhering in the composition or article, are necessarily “achieved” during the process of manufacture. The law is settled that the process of manufacture is not thereby rendered patentable. The process itself, considering the prior art, must satisfy the statutory conditions for patentability.
Appellant also argues that the “inventive concept lies basically in the process.” We cannot very well argue with appellant’s intuition as to where the “concept” lurks. We can only point out that the steps of the claimed process are old except for the alloy worked on and the product new. Appellant has achieved this new product by performing an old process on a starting material, or base metal alloy, not previously used in the process. The end-product is satisfactory, whereas prior end-products were not, due to spalling, because the old process has produced a novel article. That novelty is due to the characteristics of the starting material, not the process to which it was subjected. The selection of the starting material was, presumably, not obvious but such selection is not a category of patentable invention. 35 U.S.C. § 100. Selection resulted in a new, useful, and unobvious product on which claims have been allowed but it did not, in our view, result in either a new or unobvious process.
The decision of the board is affirmed.
Affirmed.
. Consisting of Magil, Rosa and Lidoff, Examiners-in-Chief, opinion by Magil.
. In fact the specification says (our emphasis) :
The siliconieing process employed may be one, or more, of the processes set forth in the Ihrig, Henderson, or Eekman patents set forth hereinabove, although the Eekman process is preferred.
. In which a majority of this court held that the patentability of a chemical compound did not determine the patentability of its method of preparation.